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On almost (N,p,q,)
summability of Fourier series
SHYAM LAL and HARE KRISHNA NIGAM
Abstract: In this paper a new
theorem on almost (N,p.q) summability of Fourier series, which improves a
theorem of pandey6 on (N,pn) summability of Fourier series
has been proved.
Characterization and
Anti-microbial Activity of Metal Complexes of Schiff Base derived from
4-aminosalicylic acid and benzaldehyde
KIRAN MANAGAONKAR, DIPAK VORA,
GIRISH GUNDI and DHANAJI PATIL
Abstract: Fe(II), Co(II), Ni(II),
Cu(II) and Zn(II) complexes of the Schiff base derived from 4-aminosalicylicacid
and benzaldehyde have been synthesized and characterized on the basis of
elemental analysis, magnetic moment, infra red and electronic spectral
data. These compounds are subjected to anti-microbial activity and
observed to be having more activity than the parent Schiff base and a n attempt
has been made to correlate the structure and antimicrobial activity.
Phase Behaviour and
Evaporation Study of AOT/Eugenol/Aqueous Systems
K.ANUAR, W.H.LIM, W.M.WAN
RUSMAWATI, K.DZULKEFLY, M.S.NORSIDAH and S.HAMDAN
Abstract: Ternary phase behavior
of sodium bis(2-ethylhexyl) sulfosuccinate (AOT)/Eugenol/H2O system
was constructed at 30.0±0.5°C. Liquid crystalline and isotropic regions
were identified in this system. Both of these regions decreased with the
increased of salinity. At 5M NaCl aqueous solutions, no distinct phases were
observed. Evaporation study on the isotropic region was conducted at
different humidity(22% and 85%). Evaporation rate of the isotropic region
increased with the decreased of humidity. The evaporation rate also
increased with the water content.
Trace metal geochemitry and
physico-chemical characteristics in the Ibai Estuary, Terengganu, Malaysia
KAMARUZZAMAN B.Y., SHAZILI N.A.M.,
TAHIR N., HOO E.G. and JAMIL B.T.
Abstract: Dissolved trace metal
concentrations (Cu, Mn and Pb) in Surface water were determined in the Ibai
estuary during the monsoon and non-monsoon seasons. Dissolved
concentrations for Cu and Pb has average values contamination. Meanwhile
dissolved average Mn of 0.07 ppb which were significantly low are mostly appears
to be controlled by the natural processes. On the whole, trace metal
concentrations in the dissolved metals tend to decrease from the mixing zone to
the open sea. Seasonal pattern of temperature, pH and salinity profiles
are also presented. The estuary remained marine dominated during
non-monsoon seasons, whereas freshwater dominance prevailed during monsoon
seasons. Based on the salinity distribution, Ibai estuary can be
classified as the mixed partially coastal plain estuary. The temperature
of surface and bottom waters are almost uniform or even sometimes they are
identical while pH has an inverse relationship with salinity.
Preparation and Characterization
of Polypyrrole Polymer Prepared by Non-electrochemical Method
ANUAR KASSIM, ABDUL HALIM ABDULLAH
and ZAIDI IDRIS
Abstract: Conductive Polymer
polypyrrole was chemically prepared using pyrrole as the monomer and various
oxidants such as potassium peroxydisulfate(K2S2O8),
ferric(III) chloride(FeCl3) and ferric(III) nitrate(Fe(NO3)3).
The conducting polypyrrole prepared using variable mole ratios of
oxidant/pyrrole in aqueous medium showed conductivity between
s
= 9.80x10-4 to 7.39x10-2
S cm-1. Changing the solvent in the preparation of polypyrrole
using ferric(III) nitrate as an oxidant increased the conductivity. It was
found that methanol solvent gives the highest conductivity at
s
= 6.619S cm-1. It was
also found that different type of oxidant and solvent has tremendous influence
over the conductivity. Elemental analysis showed that the ratio of pyrrole
to counter ion was found to be in the range of 2 to 7 units for the various
oxidants used and stable uP to 413°C. SEM studies of polypyrrole obtained
by using various oxidant and solvent showed this polymer is amorphous and has a
granular shape, like beads. The size of granules depends on the type of
oxidants and solvents used.
The degree of approximation
of conjugate of a function belonging to Lipschitz class by matrix summability
means of conjugate fourier serier
RAGHURAJ SINGH and YOGESH SINGH
Abstract: Qureshi determined the
degree of approximation of functions belonging to Lip a and Lip(a, p) classes. In this paper a new
theorem on the degree of approximation of conjugate at a function of LIP a class by Matrix summability means of
conjugate Fourier series has been established so that result of Qureshi come out
as a particular case of our theorem.
Comparative scores of Theoretical Mechanistic Biochemistry (TMB) on drug effects
: Viagra and Sampatrilat vs. Nisoldipine
DUNSTAN A. K. AKINTONWA
Abstract: Theoretical
Mechanistic Biochemistry (TMB) techniques were used to predict from each
structure of viagra, nisoldipine and sampatrilat respectively, the biochemical
side effect reactions, calcium channel blocker, angiotensin-converting enzyme
(ACE) and neutral/endopeptidase (NEP) inhibitor propensities and lipophilic
assessment. Viagra scored negative(-) for (1)notroso, (2)areneimine, (3)
epoxide and (4) hydroxyl free radical (*OH). Sampatrilat was (-) for
(1),(2) and (4) but positive (+) for (3). Nisoldipine was (+) for (1)-(4)
respectively.
For calcium channel blocker chelating propensity, viagra scored (1+), sampatrilat(0) and nisoldipine(4+). For ACE and NEP inhibitor assessment, viagra scored(0), nisoldipine(1+) and sampatrilat(8+). For lipophilicity assessment, viagra scored (12+). nisoldpine(10+) and Sampatrilat(8+). The uniqueness of the TMB lipophilicity of antihypertensive in hypertension and cardiovascular diseases was stressed using nisoldipine vs. enalapril and nifedipine vs. ramipril and nisoldipine vs. sampatrilat. It was concluded that viagra is in the same class as aspirin for very low calcium blocker. Nisoldipine is a powerful calcium channel blocker antihypertensive with very low ACE inhibitor potential. The *OH generated by nisoldipine was concluded to be responsible for the higher incidence of fatal and non fatal myocardial infarction in nisoldipine vs. enalapril and nisoldipine vs. remipril respectively. Sampatrilat ACE based on >C=0 and O=S=O and for NEP based on -CONH- and SO2NH- groups reacting with the -CH2OH of the serine groups of the ACE and NEP enzymes respectively was concluded to very potent with (5+)+(3+) respectively totaling (8+) as a dual inhibitor of the ACE and NEP for the lowering of blood pressure in hypertension target organs. For lipophilicity and calcium blocker potency : nicardipine (18+) > nimodipine (15+) > nisoldipine (14+) = nifedipine (14+) and for lipophilicity +ACE and NEP inhibitor potency: sampatrilat (16+) > ramipril (14+) > enalapril (11+) are the TMB calcium blockers and ACE inhibitors of choice respectively.
Viagra's TMB potential of (1+) is too low and it is therefore discountenanced as a calcium channel blocker. Similarly, nisoldipine (1+) for ACE inhibition is very low to be regarded as an ACE inhibitor antihypertensive.
Chelation Ion-Exchange Properties of Copolymer Resins Derived From
8-Hydroxyquinoline, Melamine and Formaldehyde
W. B. GURNULE, H. D. JUNEJA and L.
J. PALIWAL
Abstract: A resin (8-HQMF)
prepared by condensation of 8-hydroxyquinoline and melamine with formaldehyde in
the presence of an acid catalyst proved to be a selective chelating ion-exchange
resin for certain metals. Chelating ion-exchange properties of this resin
were studied for Cu2+, Ni2+, Co2+, Zn2+,
Cd2+, Fe3+ and Pb2+ ions. A batch
equilibrium method was employed in the study of the selectively of metal ion
uptake involving the measurements of the distribution of a given metal ion
between the resin sample and a solution containing the metal ion. The
study was carried out over a wide pH range and in medium of various ionic
strengths. The copolymer showed higher selectivity for Fe3+, Cu2+,
and Ni2+ ions than for Co2+, Zn2+, Cd2+
and Pb2+ ions.
Excess Molar polarization in binary mixtures of MIBK in nonpolar solvents
C. DWIVEDY and S. K. RAY
Abstract: The relative
permittivity of binary mixtures of Methyl isobutyl ketone (MIBK), a nuclear
extractant with nonpolar solvents is measured at frequency 455 KHz. The
relative permittivity is used to compute the linear correlation factor and
excess molar polarization of binary mixtures which throw light on the nature
molecular interaction of the polar and nonpolar molecules.
Photo Catalytic
Degradation of o-Nitro aniline
J. D. JOSHI, JABALI VORA, SANGITA
SHARMA and CHIRAG PATEL
Abstract: The photo catalytic
degradation of o-nitro aniline, a dye stuff intermediate, on semiconductor zinc
oxide powder was studied. The concentration of substrate, amount of
semiconductor, pH, light intensity, sensitizers, etc. parameters were found to
affect the kinetics of the degradation process. A probable mechanism for
the process is proposed.
Esterification
reaction of recovered palm oil with medium and long- chain alcohols for
lubricant
DZULKEFLY K. HAMDAN S. and
WEN-HUEI LIM
Abstract: Palm Oil retained in
the spent bleaching clay was extracted by using hexane, acetone and
methanol. The extracted oil was esterfied with medium and long chain
alcohols to produce both medium and long chain esters or lubricants
respectively. It was found that the quality of the recovered oil was low
with an average free fatty acid (FFA) of 11.0%, peroxide value (PV) of 10.0 and
color rate of 60R 70Y. UV spectra shows E232 and E269
of 1.6 and 1.3 respectively. No carotene is present in the extracted
oil. Among the esters studied, an alkyl ester derived from tert-butanol
showed the highest kinematic viscosity value (19.389 cSt) and the lowest was
derived from octanol (8.763 cSt). Result also showed that the viscosity of
alkyl esters decreased withthe increase of temperature from 60 to 100°C.
Computerization-Some
Issues
VIJAY ATHAVALE and R. K.
SINGH
Abstract: This paper puts light
on the various issues that need to be tackled when any organization decides to computerize.
It analyses the reasons why many organization have failed to utilize the power
of computers to the desired level and discusses various managerial and technical
problems faced during computerization.
Parent children model
using FCM to study dropouts in primary education
W. B. VASANTHA and PRAMODH
Abstract: In this paper we analyze
the cause for dropouts in primary education using FCMs. The major issue of
today is the literacy percentage of a nation which in turn boils down to the
labelling of the nation as a developed or developing or underdeveloped
one. Unless every one gets atleast the primary education one nation cannot
claim it to be even a developing one. Though the government has brought
out many schemes for compulsory primary education still the dropout percentage
is very high. Most of the schemes are difficult to implement and even
granted the schemes are implemented still the dropout percentage remains the
same.
Study of molecular
association in the binary mixtures of alcohols in toluene
C. DWIVEDY, S. K. CHAKRAVARTY
and S. K. RAY
Abstract: Excess dielectric
permittivity, mutual correlation factor and excess Gibbs energy of mixing in the
binary mixtures of alcohols (methanol, n-propanol, n-butanol) and toluene have
been evaluated using the dielectric probe. These parameters have been
utilized to throw light on the nature of molecular dipoles of the polar liquids
in these binary mixtures.
Physico-chemical Properties of
Hausa Melon Seed
M. O. OLADIMEJI, A. O.
ADEBAYO and A. H. ADEGBESAN
Abstract:
Physico-Chemical properties of oil from Hausa melon seed (Cucumeropsis edulis)
extracted with petroleum ether(BP40-60ºC) were determined. The results
showed that the oil may be unsuitable for soap making and that the degree of
unsaturation is low. The functional properties indicated that Hausa melon
flour can be used as food additive for the production of sausage, soap and cake.
Unsteady Free
Convective MHD flow of a Viscous Fluid in a Vertical Channel
N. P. SINGH, AJAY KUMAR
SINGH, M. K. YADAV and ATUL KUMAR SINGH
Abstract: The
present paper is concerned with the study of unsteady free convective flow of an
electrically conducting, incompressible, viscous fluid through a vertical
channel in the presence of a magnetic field of constant magnetic intensity
applied normal to the walls of the channel. The effects of various
parameters on the velocity field and skin-friction have been discussed with the
help of graph and table respectively.
Stochastic
analysis of a system having one Blast Furnace and two rolling machines
S. K. SINGH and V. K. PATHAK
Abstract: This
paper deals with the stochastic modeling and configurational analysis of a steel
processing system having one blast furnace and two identical rolling machines.
The raw materials that are in the form of blooms are heated up to specific
temperature in the blast furnace and afterwards sent to rolling machine which
gives them specific shapes of required sizes. Failure time distribution of
the machines are taken to be negative exponential while the repair time and
preventive maintenance time distribution are taken to be arbitrary. Two
repairmen, one for blast furnace and other for rolling machines, are used to
repair the failed units. In small scale Industries, most of the works are
done manually. Using regeneration point technique, several measures of the
system such as mean time to system failure, point wise availability of the
system, expected busy period of the repairman and expected profit earned by the
system, are obtained. At last some graphs are plotted to highlight the
results.
Toxicological
studies of 5-methyl azo-dye stuffs and it's complexes to the air breathing fish
H.fossilis
SMITA JOSHI, SONAL NEMAWARKAR AND
SHILAJA BIRLA
Abstract: This
paper deals with the studies of toxic effect of complexes of 5 methylazodye 3d
transition metal ions. For this purpose sublethal, LD50 & LD
doses were determined by taking different conc. of 5-methyl azo-dye & it's
complexes with Co2+ & Cu2+ ions. The extent of
lethality was measured by behavioral changes all over the body of H.fossilis on
exposure to azodyes and it's complexes.